Can I use frozen broccoli?

Yes. Frozen broccoli works well here. Just let it cook a couple of minutes longer on saute.

Is this Instant Pot beef and broccoli spicy?

No, it is savory and slightly sweet. You can add heat if you like.

Chuck roast and flank steak are my favorites. Both turn tender and flavorful.

The most popular Instant Pot recipe! Much better than take-out! Feel free to upgrade and add mushrooms, bell peppers and anything you like.

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Put canola oil in the Instant Pot and select "Saute".
When the oil is ready, brown the meat in batches.
Stir in the beef broth, garlic, soy sauce, brown sugar and sesame oil. Stir until the sugar is dissolved.
Lock the lid in place. Cook at high pressure for 10 minutes. Make sure the valve is set to the sealing position.
When the cooking time ends, do a quick pressure release. (Set the valve to the venting position and when the valve drops, carefully remove the lid)
Add the cornstarch and water mixture and stir until smooth.
Select "saute", add the broccoli and stir a bit.
Close the Instant Pot and let the broccoli cook for 3 minutes (fresh) or 5 minutes (frozen) on saute (no need for pressure cooking).
Open the lid, serve and enjoy!